李福军 - 南开大学

个人简介

2015. 9 - Professor, Nankai University 2015. 4 - 2015. 8 Postdoc. researcher, AIST (Tsukuba), Japan 2012. 1 - 2015. 3 Project researcher, University of Tokyo, Japan 2007. 9 - 2011. 9 Ph.D, University of Hong Kong

研究领域

(i) Alkaline-metal ion batteries The alkaline-metal ion batteries operate with very similar reaction mechanism, namely, insertion/extraction of alkaline ions into/from a cathode and the corresponding extraction/insertion of alkaline-metal ions from and into an anode. The life span of the batteries mainly depends on the reversibility of electrodes during cycles. Searching for stable electrodes and understanding the kinetics of alkaline-metal ions and charge compensation in electrodes are crucial for battery performance improvement. (ii) Metal-air batteries Our research is mainly related to Li-, Na- or K-air batteries. The reaction mechanism is dependent on the various discharge products due to their thermodynamic stability. Big challenges faced by such metal-air batteries are the low decomposition efficiency of discharge products, stability of electrolytes and electrodes against oxygen radicals generated in a charging process, and shuttling effect of the dissolved discharge products. How to alleviate or solve these problems and hence improve the battery performance is the focus of our research.

近期论文

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Yaohui Huang, Jiarun Geng, Zhuoliang Jiang, Meng Ren, Bo Wen, Jun Chen, Fujun Li*, Solvation Structure with Enhanced Anionic Coordination for Stable Anodes in Lithium-Oxygen Batteries, Angew. Chem. Int. Ed. 2023, DOI: 10.1002/anie.202306236. Jiarun Geng, Youxuan Ni, Zhuo Zhu, Quan Wu, Suning Gao, Weibo Hua, Sylvio Indris, Jun Chen, Fujun Li*, Reversible Metal and Ligand Redox Chemistry in Two-Dimensional Iron–Organic Framework for Sustainable Lithium-Ion Batteries, J. Am. Chem. Soc. 2023, 145, 1564. Meng Ren, Shuo Zhao, Suning Gao, Tong Zhang, Machuan Hou, Wei Zhang, Kun Feng, Jun Zhong, Weibo Hua, Sylvio Indris, Kai Zhang, Jun Chen, Fujun Li*, Homeostatic Solid Solution in Layered Transition-Metal Oxide Cathodes of Sodium-Ion Batteries. J. Am. Chem. Soc. 2023, 145, 224. Hengyi Fang, Suning Gao, Meng Ren, Yaohui Huang, Fangyi Cheng, Jun Chen, Fujun Li*, Dual-Function Presodiation with Sodium Diphenyl Ketone towards Ultra-stable Hard Carbon Anodes for Sodium-Ion Batteries, Angew. Chem. Int. Ed. 2023, 62, e202214717. Chenchen Wang, Kuan Wang, Meng Ren, Yaohui Huang, Kai Zhang, Changzhong Liao, Kaimin Shih, Pengfei Yan*, Fujun Li*, Interfacial Chemistry Enables Highly Reversible Na Extraction/Intercalation in Layered-Oxide Cathode Materials, Chinese J. Chem., 2023, DOI: 10.1002/cjoc.202200835. Qingliang Lv, Zhuo Zhu, Youxuan Ni, Bo Wen, Zhuoliang Jiang, Hengyi Fang, Fujun Li*, Atomic Ruthenium-Riveted Metal–Organic Framework with Tunable d-Band Modulates Oxygen Redox for Lithium–Oxygen Batteries, J. Am Chem. Soc. 2022, 144, 23239. Zhuoliang Jiang, Yaohui Huang, Zhuo Zhu, Suning Gao, Qingliang Lv, Fujun Li*, Quenching singlet oxygen via intersystem crossing for a stable Li-O2 battery, PNAS 2022, 119, e2202835119. Xunzhu Zhou, Qiu Zhang, Zhuo Zhu, Yichao Cai, Haixia Li, Fujun Li*, Anion Reinforced Solvation for Gradient Inorganic-Rich Interphase Enables High-Rate and Stable Sodium Batteries, Angew. Chem. Int. Ed. 2022, 61, e202205045. Zhuo Zhu,‡ Qingliang Lv,‡ Youxuan Ni, Suning Gao, Jiarun Geng, Jing Liang, Fujun Li*, Internal Electric Field and Interfacial Bonding Engineered Step-Scheme Junction for a Visible-Light-Involved Lithium-Oxygen Battery, Angew. Chem. Int. Ed. 2022, 61, e202116699. Qingliang Lv,‡ Zhuo Zhu,‡ Youxuan Ni, Jiarun Geng, Fujun Li*, Spin-State Manipulation of Two-Dimensional Metal-Organic Framework with Enhanced Metal-Oxygen Covalency for Lithium-Oxygen Batteries，Angew. Chem. Int. Ed. 2022, 61, e202114293. Dongfeng Du, Zhuo Zhu, Kwong-Yu Chan, Fujun Li*, Jun Chen, Photoelectrochemistry of Oxygen in Rechargeable Li–O2 Batteries, Chem. Soc. Rev. 2022, 51, 1846. Fujun Li*, Yan Yu*, Jun Lu*, Energy Spotlight: Inhibiting the Growth of Lithium Dendrites, ACS Energy Lett. 2022, 7, 1125. Zhuoliang Jiang, Bo Wen, Yaohui Huang, Haixia Li, Fujun Li*, Metal-Organic Frameworks based Lithium-Oxygen Batteries, Chem. Eur. J. 2022, 28, e202202130. Yaohui Huang, Bo Wen, Zhuoliang Jiang, Fujun Li*, Solvation chemistry of electrolytes for stable anodes of lithium metal batteries, Nano Research 2022, DOI: 10.1007/s12274-022-4839-8. Quan Wu, Tong Zhang, Jiarun Geng, Suning Gao, Hua Ma, Fujun Li*, Anionic Redox Chemistry for Sodium-Ion Batteries: Mechanisms, Advances, and Challenges, Energy Fuels 2022, 36, 8081. Siyuan Li, Yangyang Zhang, Kaixiang Lei*, Qian Yang, Zheng Liu, Kezhu Jiang, Fujun Li*, Qiongqiong Lu, Daria Mikhailova, Shijian Zheng*, Na+/Vacancy Disordered Manganese-Based Oxide Cathode with Ultralow Strain Enabled by Tuning Charge Distribution, J. Mater. Chem. A, 2022, 10, 10391. Bo Wen, Zhuo Zhu, Fujun Li*, Advances and Challenges on Cathode Catalysts for Lithium Oxygen Batteries, Journal of Electrochemistry, DOI: 10.13208/j.electrochem.2215001. Yong Lu, Qiu Zhang, Fujun Li, Jun Chen*, Emerging Lithiated Organic Cathode Materials for Lithium-Ion Full Batteries, Angew. Chem. Int. Ed. 2022, 135, e202216047. Yizeng Wu, Bo Zhao, Xuewei Zhao, Lei Han, Yuanyuan Shang, Zhiqiang Niu, Yulong Liang, Xinbo Zhang, Zhuoliang Jiang, Fujun Li, Anyuan Cao*, Compressible, gradient-immersion, regenerable carbon nanotube sponges as high-performance lithium–oxygen battery cathodes, Materials Today, 2022, 59, 68. Zhuo Zhu, Youxuan Ni, Qingliang Lv, Jiarun Geng, Wei Xie, Fujun Li*, Jun Chen, Surface plasmon mediates the visible light-responsive lithium-oxygen battery with Au nanoparticles on defective carbon nitride, PNAS 2021, 118, e2024619118. Chenchen Wang, Luojia Liu, Shuo Zhao, Yanchen Liu, Yubo Yang, Haijun Yu, Suwon Lee, Gi-Hyeok Lee, Yong-Mook Kang, Rong Liu, Fujun Li*, Jun Chen, Tuning local chemistry of P2 layered-oxide cathode for high energy and long cycles of sodium-ion battery, Nat. Commun. 2021, 12, 2256. Qingliang Lv,§ Zhuo Zhu,§ Shuo Zhao, Liubin Wang, Qing Zhao, Fujun Li*, Lynden A. Archer*, Jun Chen*, Semiconducting Metal−Organic Polymer Nanosheets for a Photoinvolved Li−O2 Battery under Visible Light, J. Am Chem. Soc. 2021, 143, 1941. Shuo Zhao, Chenchen Wang, Dongfeng Du, Lin Li, Shulei Chou*, Fujun Li*, Jun Chen, Bifunctional Effects of Cation Additive on Na-O2 Batteries, Angew. Chem. Int. Ed. 2021, 60, 3205. Zhiqiang Luo, Silin Zheng, Shuo Zhao, Xin Jiao, Zongshuai Gong, Fengshi Cai, Yueqi Duan, Fujun Li*, Zhihao Yuan*, High Energy Density Aqueous Zinc-Benzoquinone Battery Enabled by Carbon Cloth with Multiple Anchoring Effects, J. Mater. Chem. A 2021, 9, 6131. Yanchen Liu, Chenchen Wang, Shuo Zhao, Lin Zhang, Kai Zhang, Fujun Li*, Jun Chen, Mitigation of Jahn-Teller Distortion and Na+/Vacancy Ordering in Distorted Manganese Oxide Cathode Material by Li Substitution, Chem. Sci. 2021, 12, 1062. Xunzhu Zhou, Qiu Zhang, Zhimeng Hao, Yilin Ma, Oleg A. Drozhzhin, Fujun Li*, Unlocking the Allometric Growth and Dissolution of Zn Anodes at Initial Nucleation and Early Stage with Atomic Force Microscopy, ACS Appl. Mater. Interfaces 2021, 13, 53227. Yanchen Liu, Chenchen Wang, Meng Ren, Hengyi Fang, Zhuoliang Jiang, Fujun Li*, Ultralow-strain Ti substituted Mn-vacancy layered oxides with enhanced stability for sodium-ion batteries, J. Energy Chem. 2021, 63, 351. Jiarun Geng,§ Zhuo Zhu,§ Youxuan Ni, Fangyi Cheng, Fujun Li*, Jun Chen, Biaxial strained dual-phase palladium-copper bimetal boosts formic acid electrooxidation, Nano Res. 2022, 15, 280. Lin Zhang, Chenchen Wang, Yanchen Liu, Meng Ren, Juan Du, Aibing Chen*, Fujun Li*, Suppressing interlayer-gliding and Jahn-Teller effect in P2-type layered manganese oxide cathode via Mo doping for sodium-ion batteries, Chem. Eng. J. 2021, 426, 130813. Hengyi Fang, Suning Gao, Zhuo Zhu, Meng Ren, Quan Wu, Haixia Li, Fujun Li*, Recent Progress and Perspectives of Sodium Metal Anodes for Rechargeable Batteries, Chem. Res. Chinese Universities, 2021, 37, 189. Liubin Wang, Youxuan Ni, Xuesen Hou, Li Chen, Fujun Li*, Jun Chen, A two-dimensional metal-organic polymer enabled by robust nickel-nitrogen and hydrogen bonds for exceptional sodium-ion storage, Angew. Chem. Int. Ed. 2020, 59, 22126. Dongfeng Du, Shuo Zhao, Zhuo Zhu, Fujun Li*, Jun Chen, Photo-excited oxygen reduction and oxygen evolution reactions enabling a high-performance Zn-air battery, Angew. Chem. Int. Ed.2020, 59, 18140. Yuwen Luo, Feipeng Zheng*, Luojia Liu, Kaixiang Lei, Xuesen Hou, Gang Xu, Hui Meng, Jifu Shi*, Fujun Li*, A High-Power Aqueous Zinc–Organic Radical Battery with Tunable Operating Voltage Triggered by Selected Anions, ChemSusChem 2020, 13, 2239. Xunzhu Zhou, Yong Lu, Qiu Zhang, Licheng Miao, Kai Zhang, Zhenhua Yan, Fujun Li*, Jun Chen, Exploring the Interfacial Chemistry between Zinc Anodes and Aqueous Electrolytes via an In Situ Visualized Characterization System, ACS Appl. Mater. Interfaces 2020, 12, 49, 55476. Xiaoxiao Bai, Jiarun Geng, Shuo Zhao, Haixia Li, Fujun Li*, Tunable Hollow Pt@Ru Dodecahedra via Galvanic Replacement for Efficient Methanol Oxidation, ACS Appl. Mater. Interfaces 2020, 12, 23046. Huanhuan Dong, Shuo Zhao, Xuesen Hou, Liubin Wang, Haixia Li, Fujun Li*, Nitroxide radical cathode material with multiple electron reactions, J. Energy Chem. 2021, 58, 110. Jiarun Geng, Zhuo Zhu, Xiaoxiao Bai, Fujun Li*, Jun Chen, Hot-Injection Synthesis of PtCu3 Concave Nanocubes with High-Index Facets for Electrocatalytic Oxidation of Methanol and Formic Acid, ACS Appl. Energy Mater. 2020, 3, 1010. Meng Ren, Hengyi Fang, Chenchen Wang, Haixia Li, Fujun Li*, Advances on Manganese-Oxide-Based Cathodes for Na-Ion Batteries, Energy & Fuels 2020, 34, 13412. Shuo Zhao, Lin Li, Fujun Li*, Shulei Chou*, Recent Progress on Understanding and Constructing Reliable Na Anode for Aprotic Na-O2 Batteries: a mini review, Electrochem. Commun. 2020, 118, 106797. Kaixiang Lei*, Jing Wang, Cong Chen, Siyuan Li, Shiwen Wang*, Shijian Zheng, Fujun Li*, Recent progresses on alloy-based anodes for potassium-ion batteries, Rare Met. 2020, 39, 989. Quan Wu, Yanchen Liu, Zhuo Zhu, Haixia Li, Fujun Li*, 钠离子电池碳负极材料的研究进展, Sci. Sin. Chim. 2020, 51, 862. Zihan Shen, Mengqiu Cao, Zili Zhang, Jun Pu, Chenglin Zhong, Jiachen Li, Haixia Ma, Fujun Li, Jia Zhu, Feng Pan, Huigang Zhang* , Efficient Ni2Co4P3 Nanowires Catalysts Enhance Ultrahigh‐Loading Lithium–Sulfur Conversion in a Microreactor‐Like Battery, Adv. Funct. Mater. 2020, 30, 1906661. Junlun Zhu, Wei Nie, Qin Wang, Wei Wen*, Xiuhua Zhang, Fujun Li, Shengfu Wang* , A competitive self-powered sensing platform based on a visible light assisted zinc–air battery system, Chem. Commun. 2020, 56, 5739. Liubin Wang, Albert A. Voskanyan*, Kwong Yu Chan*, Bin Qin, Fujun Li, Combustion Synthesized Porous Bismuth/N-Doped Carbon Nanocomposite for Reversible Sodiation in a Sodium-Ion Battery, ACS Appl. Energy Mater. 2020, 3, 565. Kaixiang Lei, Zhuo Zhu, Zhengxuan Yin, Pengfei Yan, Fujun Li*, Jun Chen, Dual Interphase Layers In Situ Formed on a Manganese-Based Oxide Cathode Enable Stable Potassium Storage, Chem 2019, 5, 3320. Dongdong Zhu, Qiancheng Zhao, Guilan Fan, Shuo Zhao, Liubin Wang, Fujun Li*, Jun Chen, Photo‐Induced Oxygen Reduction Reaction Boosts The Output Voltage of Zn‐Air Battery, Angew. Chem. Int. Ed. 2019, 58, 12460. Zhuo Zhu, Xiaomeng Shi, Guilan Fan, Fujun Li*, Jun Chen, Photo‐energy conversion and storage in an aprotic Li‐O2 battery, Angew. Chem. Int. Ed. 2019, 58, 19021. Chenchen Wang, Dongfeng Du, Mingming Song, Yunhai Wang, Fujun Li*, A High‐Power Na3V2(PO4)3‐Bi Sodium‐Ion Full Battery in a Wide Temperature Range, Adv. Energy Mater. 2019, 9, 1900022. Yuwen Luo, Luojia Liu, Kaixiang Lei, Jifu Shi*, Gang Xu, Fujun Li*, Jun Chen, Nonaqueous potassium-ion hybrid capacitor enabled by two-dimensional diffusion pathways of dipotassium terephthalate, Chem. Sci. 2019, 10, 2048. Zhuo Zhu, Xiaomeng Shi, Dongdong Zhu, Liubin Wang, Kaixiang Lei, Fujun Li*, A Hybrid Na//K+-Containing Electrolyte//O2 Battery with High Rechargeability and Cycle Stability, Research 2019, 2019, 6180615. Shuo Zhao, Bin Qin, Kwong-Yu Chan*, Chi-Ying Vanessa Li, Fujun Li*, Recent development of aprotic Na-O2 batteries, Batteries & Supercaps 2019, 2, 725. Mingming Song, Chenchen Wang, Dongfeng Du, Fujun Li*, Jun Chen, A high-energy-density sodium-ion full battery based on tin anode, Sci. China Chem. 2019, 62, 616. 刘彦辰, 王晨晨, 李海霞, 李福军*, 钠离子电池无机负极材料的研究进展, Sci. Sin. Chim. 2019, 49, 1351. Yixin Li, Luojia Liu, Chang Liu, Yong Lu, Ruijuan Shi, Fujun Li, Jun Chen*, Rechargeable Aqueous Polymer-Air Batteries Based on Polyanthraquinone Anode, Chem 2019, 5, 1. Yue Yuan, Chenchen Wang, Kaixiang Lei, Haixia Li, Fujun Li*, Jun Chen, Sodium-Ion Hybrid Capacitor of High Power and Energy Density, ACS Cent. Sci. 2018, 4, 1261. Zhiqiang Luo, Luojia Liu, Jiaxin Ning, Kaixiang Lei, Yong Lu, Fujun Li*, Jun Chen, A Microporous Covalent Organic Framework with Abundant Accessible Carbonyls for Lithium-ion Batteries, Angew. Chem. Int. Ed. 2018, 57, 9443 (VIP). Kaixiang Lei, Chenchen Wang, Luojia Liu, Yuwen Luo, Chaonan Mu, Fujun Li*, Jun Chen, A Porous Network of Bismuth Used as Anode Material for High-Energy-Density Potassium-Ion Batteries, Angew. Chem. Int. Ed. 2018, 57, 4687. Liubin Wang, Youxuan Ni, Kaixiang Lei, Huanhuan Dong, Sen Tian, Fujun Li*, 3D Porous Tin Enabled by Tuneable Redox Potential as An Advanced Electrode for Sodium‐Ion Battery, ChemSusChem 2018, 11, 3376 (VIP). Yuhou Pei, Chaonan Mu, Haixia Li, Fujun Li*, Jun Chen, Low-Cost K4Fe(CN)6 as A High-Voltage Cathode for Potassium-Ion Batteries, ChemSusChem 2018, 11, 1285. Liubin Wang, Chaonan Mu, Haixia Li, Fujun Li*, A dual-function battery for desalination and energy storage, Inorg. Chem. Front. 2018, 5, 2522. Liubin Wang, Chenchen Wang, Fujun Li*, Fangyi Cheng and Jun Chen, In situ synthesis of Bi nanoflakes on Ni foam for sodium-ion batteries, Chem. Commun. 2018, 54, 38. Luojia Liu, Licheng Miao, Lin Li, Fujun Li, Yong Lu, Zhenfeng Shang*, Jun Chen*, Molecular Electrostatic Potential: A New Tool to Predict the Lithiation Process of Organic Battery Materials, J. Phys. Chem. Lett. 2018, 9, 3573. Jing Meng, Fangming Liu, Zhenhua Yan, Fangyi Cheng*, Fujun Li, Jun Chen, Spent alkaline battery-derived manganese oxides as efficient oxygen electrocatalysts for Zn–air batteries, Inorg. Chem. Front. 2018, 5, 2167.